Description
一、present
In industrial hydrogen purification by pressure swing adsorption (PSA), the adsorbents generally adsorb the easily adsorbed components out of the gas mixture at ambient temperature and high pressure, while the not easily adsorbed components (such as hydrogen) flow out from one end of the bed as the product, and then the adsorbent bed is depressurized to desorb the adsorbates and discharge them out from the other end of the bed, thus gas separation and purification is realized, and the adsorbents are regenerated at the meantime.However, in general PSA process, there are two ways to regenerate the adsorbents, one is to "purge" the bed with product gas to reduce the partial pressure of the adsorbed impurities and displace the desorbed impurities. The advantage is that it can be operated under normal pressure, but the disadvantage is that more product gas is lost; Another regeneration method is using vacuum, desorbing the adsorbed impurities under negative pressure, which is commonly known as vacuum pressure swing adsorption (VPSA or VSA). The advantage of VPSA process is high product yield, but the disadvantage is that a vacuum pump is required, and the energy consumption of the unit is relatively higher. In practice, which method of the above to use depends on feed gas composition, product purity and yield requirements, etc.
二、Technical features
1.Simple, advanced and reliable process flow with strong applicability of feed gases;
2.High hydrogen product purity, from 98% to 99.999%;
3.High hydrogen recovery, from 60% to 99% depending on gas source and product conditions;
4.Wide operating pressure range of 0.2-7.0MPaG, low energy consumption, high flexibility of 20-120%, and continuous on-stream time over 4 years;
5.High degree of automation, with functions such as self-adaptive adjustment and automatic fault diagnosis, easy startup and shutdown, and unmanned automatic control.
三、Applications
变换气,甲醇裂解气,甲醇驰放气、合成氨尾气,炼厂加氢低分气、焦炉煤气、水煤气、催化干气,重整氢等各类含氢气体。
Flow Schematic
Cases
list | Customer | Scale | Raw gas | Purity | Process Route |
一 | Typical | ||||
1 | 中石化四川维尼纶厂 | 7000Nm3/h | Methanol off-gas | 99.9% | PSA(It's been in operation for 20 years and has been certified by Sinopec.) |
2 | 苏丹喀土穆炼油厂 | 11000Nm3/h | FCC dry gas | 99.9% | VPSA(China's largest export hydrogen plant) |
3 | AIR PRODUCT | 2000Nm3/h | Syngas | 99.9% | PSA(3.5MPa(G)) |
4 | 中石化南京化学工业公司(2套) | 63000Nm3/h | Fertiliser syngas | 99.9% | VPSA(4.0MPa(G)) |
5 | 中石化福建炼化公司 | 80000Nm3/h | POX tail gas | 99.9% | PSA(4.5MPa(G)) |
6 | 大唐电力化工公司 | 10000Nm3/h | Methanol off-gas | 99.9% | PSA(5.0MPa(G)) |
二 | Reformulated PSA Typical Performance | ||||
1 | 中海油惠州炼化公司二期 | 120000Nm3/h | Reforming gas+Low fraction gas | 99.90% | PSA |
2 | 中国石油独山子石化分公司 | 140000Nm3/h | Reforming gas | 99.90% | PSA |
3 | 中国石化湛江东兴石油化工有限公司 | 100000Nm3/h | Reforming gas | 99.90% | PSA |
4 | 厦门腾龙芳烃有限公司 | 200000Nm3/h | Reforming gas | 99.90% | PSA |
三 | Typical performance of coal-to-hydrogen PSA | ||||
1 | 中海油惠州炼化公司二期 | 200000Nm3/h | POXSyngas | 99.90% | PSA |
2 | 宁波中金石化有限公司 | 108000Nm3/h | Syngas+Low-content gas | 99.90% | 一段VPSA+二段PSA |
3 | 中国石化湛江东兴石油化工有限公司 | 2*90000Nm3/h | Syngas | 99.90% | PSA |
四 | Typical performance of tail gas PSA recovery | ||||
1 | 中国石化北海炼化有限责任公司 | 32000 Nm3/h | Refinery dry gas | 99.90% | VPSA |
2 | 中国石油锦西石化分公司 | 22000 Nm3/h | Hydrogen-containing gases | 99.90% | VPSA |
3 | 中国石化海南炼油化工有限公司 | 20000 Nm3/h | Refinery dry gas | 99.90% | VPSA |
五 | Typical performance of PSA for transformed gas | ||||
1 | 中石油大连石化公司 | 2×100000Nm3/h | Conversion gas | 99.90% | PSA |
2 | 中国石化股份有限公司武汉分公司 | 80000Nm3/h | Conversion gas | 99.90% | PSA |
3 | 中石化股份有限公司天津分公司 | 100000Nm3/h | Conversion gas | 99.90% | PSA |
六 | Typical Performance of Coke Oven Gas PSA | ||||
1 | 河南金江炼化有限责任公司 | 33000 Nm3/h | Coke oven gas | 99.90% | TSA+PSA |
2 | 宝钢广东湛江钢铁基地项目 | 2600 Nm3/h | Coke oven gas | 99.999% | TSA+PSA |
七 | VPSA-CO2 | ||||
1 | 辽宁华锦通达化工股份有限公司炼化分公司 | 20000 Nm3/h | Hydrogen PSA tail gas | 95% | VPSA |
2 | 宁波中金石化有限公司 | 108000Nm3/h | Syngas | 99.90% | 一段VPSA |
八 | C2+Recycling Projects | ||||
1 | 黑龙江省龙油石油化工股份有限公司 | 40000 Nm3/h | Catalytic dry gas | C2+ | VPSA |
九 | Pressure change adsorption EPC project | ||||
1 | 内蒙古伊泰化工有限责任公司 | 49000 Nm3/h;27000 Nm3/h | Permeate gas;Purification gas | 99.90% | PSA |
2 | 黑龙江省龙油石油化工股份有限公司 | 80000 Nm3/h;30000 Nm3/h | Conversion gas;Low-content gas | 99.90% | PSA |
3 | 黑龙江省龙油石油化工股份有限公司 | 40000 Nm3/h | Catalytic dry gas | C2+ | VPSA |
4 | 厦门腾龙芳烃有限公司 | 200000Nm3/h | Reformulated gas | 99.90% | PSA |